Your No. 1 visual clue: good tint has small, clean edges
To tell if a car has a quality tint, see how close the film comes to the window edge, and take note of how consistent and clean the line is. A top-notch installer uses computerized templates that pre-cut the film as much as possible, resulting in a line that's close to the edge of the window pane and doesn't waver. As opposed to my poor old Mustang, above, where there’s a significant gap and it looks all-around shitty.
And purple is the enemy
Only one person could properly get away with purple windows (RIP Prince!), but you'd never know it given the tremendous number of cars on the road with tint that has turned purple with age. It's an obvious sign that the film is of the most basic quality possible, a vinyl sheet with dyes that fade over time.